低浓度挥发性有机物吸附浓缩材料的研究进展

由于挥发性有机物（VOCs）会对环境造成严重的危害，因此VOCs的处理一直备受人们的关注，但发展高效的VOCs处理技术仍然存在严峻的挑战。本文针对大风量、低浓度VOCs的处理展开了综述，重点围绕吸附、催化燃烧处理展开讨论。对于大风量的低浓度VOCs，虽然浓度较低但VOCs排放量非常巨大。通过VOCs浓缩技术，提高浓度减少风量成为降低VOCs处理成本的有效途径。其中，发展高性能VOCs吸附材料是VOCs浓缩技术的关键。阐明了活性炭、分子筛等重要吸附材料的性质及其吸附VOCs的原理，并对吸附材料性质和VOCs种类对吸附效果的影响进行了探讨。展望了活性炭浓缩-催化燃烧技术和分子筛转轮浓缩-催化燃烧技术在大风量的低浓度VOCs处理中的应用前景。     

并联有源滤波器的改进重复控制策略研究

针对三相整流负载产生的6k±1次谐波,提出静止坐标系下的改进型6k±1重复控制策略。同时将比例控制与改进型重复控制相结合,设计改进重复控制并联比例的复合控制结构。为减小改进重复控制中延时环节不为整数的影响,采用基于Lagrange插值近似的FIR滤波器逼近分数延时特性。最后对系统进行稳定性分析和详细设计方法进行推导。通过Matlab仿真验证改进重复控制策略能有效跟踪6k±1次谐波且具有良好的补偿效果,动态响应较快。     

Redox‐Active Polymers Connecting Living Microbial Cells to an Extracellular Electrical Circuit

Microbial electrochemical systems in which metabolic electrons in living microbes have been extracted to or injected from an extracellular electrical circuit have attracted considerable attention as environmentally‐friendly energy conversion systems. Since general microbes cannot exchange electrons with extracellular solids, electron mediators are needed to connect living cells to an extracellular electrode. Although hydrophobic small molecules that can penetrate cell membranes are commonly used as electron mediators, they cannot be dissolved at high concentrations in aqueous media. The use of hydrophobic mediators in combination with small hydrophilic redox molecules can substantially increase the efficiency of the extracellular electron transfer process, but this method has side effects, in some cases, such as cytotoxicity and environmental pollution. In this Review, recently‐developed redox‐active polymers are highlighted as a new type of electron mediator that has less cytotoxicity than many conventional electron mediators. Owing to the design flexibility of polymer structures, important parameters that affect electron transport properties, such as redox potential, the balance of hydrophobicity and hydrophilicity, and electron conductivity, can be systematically regulated.     

Active Metamaterials with Negative Static Electric Susceptibility

Although well-established textbook arguments suggest that static electric susceptibility χ⁽⁰⁾ must be positive in “all bodies,” it has been pointed out that materials that are not in thermodynamic equilibrium are not necessarily subject to this restriction. Media with inverted populations of atomic and molecular energy levels have been predicted theoretically to exhibit a χ⁽⁰⁾ < 0 state, however the systems envisioned require reduced temperature, reduced pressure, and an external pump laser to maintain the population inversion. Further, the existence of χ⁽⁰⁾ < 0 has never been confirmed experimentally. Here, a completely different approach is taken to the question of χ⁽⁰⁾ < 0 and a design concept to achieve “true” χ⁽⁰⁾ < 0 is proposed based on active metamaterials with internal power sources. Two active metamaterial structures are fabricated that, despite still having their power sources implemented externally for reasons of practical convenience, provide evidence in support of the general concept. Effective values are readily achieved at room temperature and pressure and are tunable throughout the range of stability −1 < χ⁽⁰⁾ < 0, resulting in experimentally-determined magnitudes that are over one thousand times greater than those predicted previously. Since χ⁽⁰⁾ < 0 is the missing electric analog of diamagnetism, this work opens the door to new technological capabilities such as stable electrostatic levitation.     

基于功频下垂控制的光伏并网发电系统惯量阻尼机理研究

针对光伏以低惯量、弱阻尼的特征大规模接入电网，给电网稳定性带来不利影响的问题，基于功频下垂控制的光伏并网发电系统，借鉴经典电气转矩分析法，从物理机制层面上分析影响系统惯量、阻尼以及同步能力的作用规律。研究结果表明对于控制参数的影响规律而言，惯量特性主要受功率环的比例系数Kp影响，且随Kp的增大而增强；阻尼特性受频率下垂系数Dp影响比较明显，且随Dp的增大而减弱；同步特性只受功率环的比例积分系数Ki影响，且随Ki的增大而增强。通过仿真验证了理论分析的正确性。     

铸态Mg-xSn-1Mn合金的显微组织和阻尼性能

采用光学显微镜(OM)、维氏硬度计、热动态分析仪、X射线衍射(XRD)、多功能内耗仪等,研究了Sn含量对Mg-xSn-1Mn合金显微组织、阻尼性能和力学性能的影响。结果表明:当Sn含量从2%增加到8%时,Mg-xSn-1Mn合金的枝晶间隙呈现细化的趋势,硬度从43.84 HV0.1增加至54.00 HV0.1,呈单调增加的趋势。应变无关阻尼随着Sn含量的增加呈现先增后减的趋势,在Sn含量为4%时达到最大,应变相关阻尼则随着Sn含量的增加呈现逐渐减小的趋势。在低温阶段,相同Sn含量的合金的阻尼随着频率的增大呈现增加的趋势;但在高温下,阻尼值在低频时的上升速率比高频时快,并随着温度的升高,低频阻尼和高频阻尼趋向于相等。当Sn含量不同时,随着温度的升高,Sn含量较高的合金的阻尼值上升速率变快。     

起重机械防碰装置试验系统的设计

防碰装置是起重机械重要的安全防护装置,其性能质量直接关系到人员和设备安全。常规的防碰装置性能试验方法难以保证试验数据的精度和可靠性。针对防碰装置的工作特点和试验要求,从试验原理、系统结构、运行逻辑等方面入手,设计一套能模拟防碰装置实际运行工况,自动进行性能试验和数据采集处理,精度高、重复性好的试验系统,可以有效提升防碰装置检测能力。     

HPLC-ESI-MS/MS分析黄芪蜜炙前后活性成分差异

建立了HPLC-ESI-MS/MS联用技术分析生黄芪与炙黄芪的成分，并比较两者成分差异。采用Agilent ZORBAX SB-C18色谱柱（4.6 mm×250 mm×5 μm），以0.1%甲酸乙腈溶液-0.1%甲酸水溶液为流动相进行梯度洗脱，流速1 mL/min，检测波长203 nm，柱温25 ℃；使用ESI离子源，分别在正、负离子模式下进行全扫描和二级扫描，质量扫描范围m/z 100~2000。采用该方法鉴定了生黄芪与炙黄芪中的62种成分，并对黄芪蜜炙前后的成分进行了比较，实验结果可为黄芪炮制方法的选择提供参考依据。     

大块煤破碎装置的设计与应用

岳城煤矿2135厚煤层工作面在开采实践过程中,片帮大块煤会造成带式输送机的堵塞,引发运输故障,需要停机检修。基于该问题设计了一种对大块煤进行有效破碎的装置,应用中设备操作简便,有效地解决了带式输送机机头卸载点和转载机入口的堵塞问题,为企业创造了较好的经济效益。     

双弹性板矩形空腔内噪声的有源力控制

研究了在弹性板上施加不同参数的有源力对腔内噪声进行控制的问题。构建双弹性板构成的封闭矩形声腔模型，对封闭声腔的结构 声耦合特性进行分析，推导了在封闭声腔有源力控制作用下声压计算公式，给出采用有源力控制的最优控制模型。分析了弹性板在不同参数的次级力源激励下腔内局部声场的声压级响应，并建立了仿真模型对局部声场的减噪效果进行分析。结果表明，合理选择次级力源的参数对控制效果的影响较为明显，且次级力源的个数并非越多越好。